A repository & source of cutting edge news about emerging terahertz technology, it's commercialization & innovations in THz devices, quality & process control, medical diagnostics, security, astronomy, communications, applications in graphene, metamaterials, CMOS, compressive sensing, 3d printing, and the Internet of Nanothings. NOTHING POSTED IS INVESTMENT ADVICE! REPOSTED COPYRIGHT IS FOR EDUCATIONAL USE.
We are demonstrating the optical control of a specific state of the germanium telluride (GeTe) phase change material and its integration as control element for realizing extremely efficient optically reconfigurable THz devices. The excellent contrast of the material THz electrical properties in the two dissimilar states were used for optical-induced fast modulation of THz resonances of a hybrid metamaterial based of arrays of split ring resonator metallic structures integrating GeTe patterns. We experimentally confirm for the first time the feasibility to develop all dielectric (metal free) GeTe-based THz polarizers presenting a broadband response, a high extinction ratio when the GeTe is in the metal-like phase (up to 16.5 dB) and almost transparent when the material is in the amorphous phase. The presented highly functional approach based on non-volatile, optically controlled multi-operational THz devices integrating PCMs, is extremely stimulating for generating disruptive developments like field-programmable metasurfaces or all-dielectric coding metamaterials with multifunctional capabilities for THz waves manipulation.
http://onlinelibrary.wiley.com/doi/10.1002/chem.201702218/abstract Crystal formation is a highly debated problem. We show that the crystallization of L-(+)-tartaric acid from water follows a non-classical path involving intermediate hydrated states. Analytical ultracentrifugation indicates solution clusters of the initial stages aggregate to form an early intermediate. Terahertz spectroscopy performed during water evaporation highlights a transient increase in the absorption during nucleation. This indicates the recurrence of water molecules which are expelled from the intermediate phase. Besides, a transient resonance at 750 GHz that can be assigned to a natural vibration of large hydrated aggregates vanishes after the final crystal has formed. Furthermore, THz data reveal the vibration of nanosized clusters in the dilute solution indicated by analytical ultracentrifugation. Infrared spectroscopy and wide-angle X-ray scattering highlight that the intermediate is not a crystalline hydrate. Our results demonstrate that nanoscopic intermediate units assemble to form the first solvent-free crystalline nuclei upon dehydration.
