Abstract-Terahertz spectroscopy and global analysis of the rotational spectrum of doubly deuterated Amidogen radical ND2

Mattia Melosso, Claudio Degli Esposti, Luca Dore

https://arxiv.org/abs/1712.00219

The deuteration mechanism of molecules in the interstellar medium (ISM) is still being debated. Observations of deuterium-bearing species in several astronomical sources represent a powerful tool to improve our understanding of the interstellar chemistry. The doubly deuterated form of the astrophysically interesting Amidogen radical could be a target of detection in space. In this work, the rotational spectrum of the ND2radical in its ground vibrational and electronic X2B1 states has been investigated between 588 and 1131 GHz using a frequency modulation millimeter/submillimeter-wave spectrometer. The ND2 has been produced in a free-space glass absorption cell by discharging a mixture of ND3 and Ar. Sixty-four new transition frequencies involving J values from 2 to 5 and Ka values from 0 to 4 have been measured. A global analysis including all the previous field-free pure rotational data has been performed, allowing for a more precise determination of a very large number of spectroscopic parameters. Accurate predictions of rotational transition frequencies of ND2 are now available from a few GHz up to several THz.