Abstract-Terahertz Time-Domain Polarimetry for Principal Optical Axes of Anisotropic Crystals

 

Alexander Mamrashev, Fedor Minakov, Nazar Nikolaev, Valery Antsygin, 

https://www.mdpi.com/2304-6732/8/6/213/pdf

We propose a method for measuring the terahertz properties for two principal optical axes of anisotropic crystals without optical activity using terahertz time-domain spectroscopy (THzTDS). The method put forward in this paper utilizes the inherent polarization sensitivity of the THz-TDS electro-optic detection system. We demonstrate the practical application of the method by measuring the temperature dependence of the refractive index and the absorption coefficient of a lithium triborate crystal for three optical axes.

Abstract-Anisotropic terahertz dielectric responses of sodium nitrate crystal

Xiaojian Fu,   Youting Song,   Chang Qing Sun and   Ji Zhou  

Phys. Chem. Chem. Phys., 2014, Accepted Manuscript

DOI: 10.1039/C3CP55484H
Received 28 Dec 2013, Accepted 18 Feb 2014
First published online 18 Feb 2014
http://pubs.rsc.org/en/content/articlelanding/2014/cp/c3cp55484h#!divAbstract

Terahertz (THz) spectroscopy has become an effective tool to characterize the low-frequency rotational and vibrational modes of molecules. In addition, novel THz dielectric responses and optical properties on the basis of molecular rotation and vibration have attracted lots of attention because of their potential application in THz devices. In this paper, the dielectric response of low-symmetric sodium nitrate crystal in the frequency range of 0.2-1.5 THz was experimentally demonstrated. Four absorption bands at 0.23, 0.47, 0.92, and 1.15 THz were observed in the dielectric spectra and were tentatively ascribed to the rotational motion of nitrate ions. Based on the molecular rotation mechanism, the dielectric anisotropy and dielectric resonance of the crystal were discussed in detail.