In recent years, there have been conflicting reports regarding the ultrafast photoconductive response of films of single walled carbon nanotubes (CNTs), which apparently exhibit photoconductivities that can differ even in sign. Here, we observe explicitly that the THz photoconductivity of CNT films is a highly variable quantity which correlates with the length of the CNTs, while the chirality distribution has little influence. Moreover, by comparing the photo-induced change in THz conductivity with heat-induced changes, we show that both occur primarily due to heat-generated modification of the Drude electron relaxation rate, resulting in a broadening of the plasmonic resonance present in finite-length metallic and doped semiconducting CNTs. This clarifies the nature of the photo-response of CNT films and demonstrates the need to carefully consider the geometry of the CNTs, specifically the length, when considering them for application in optoelectronic devices.
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Showing posts with label Peter Karlsen. Show all posts
Showing posts with label Peter Karlsen. Show all posts
Tuesday, May 8, 2018
Abstract-Sign inversion in the terahertz photoconductivity of single-walled carbon nanotube films
Sunday, November 19, 2017
Abstract-Influence of nanotube length and density on the plasmonic terahertz response of single-walled carbon nanotubes
Peter Karlsen, Mikhail Shuba, Chris Beckerleg, Dzmitry Yuko, Polina Kuzhir, Sergey A Maksimenko, Vitaly Ksenevich, Ho Viet, Albert Nasibulin, Reshef Tenne,
https://advance.lexis.com/search/?pdmfid=1000516&crid=32be016c-f800-410e-bff5-cd07c0196b13&pdsearchterms=16+FRD+571&pdstartin=hlct%3A1%3A1&pdtypeofsearch=searchboxclick&pdsearchtype=SearchBox&pdqttype=and&pdpsf=&ecomp=qtbd9kk&earg=pdpsf&prid=dc626330-b7ef-4d0e-b3f7-71b8244e0a8f
We measure the conductivity spectra of thin films comprising bundled single-walled carbon nanotubes (CNTs) of different average lengths in the frequency range 0.3-1000 THz and temperature interval 10-530 K. The observed temperature-induced changes in the terahertz conductivity spectra are shown to depend strongly on the average CNT length, with a conductivity around 1 THz that increases/decreases as the temperature increases for short/long tubes. This behaviour originates from the temperature dependence of the electron scattering rate, which we obtain from Drude fits of the measured conductivity in the range 0.3-2 THz for 10 μm length CNTs. This increasing scattering rate with temperature results in a subsequent broadening of the observed THz conductivity peak at higher temperatures and a shift to lower frequencies for increasing CNT length. Finally, we show that the change in conductivity with temperature depends not only on tube length, but also varies with tube density. We record the effective conductivities of composite films comprising mixtures of WS<sub>2</sub> nanotubes and CNTs vs CNT density for frequencies in the range 0.3-1 THz, finding that the conductivity increases/decreases for low/high density films as the temperature increases. This effect arises due to the density dependence of the effective length of conducting pathways in the composite films, which again leads to a shift and temperature dependent broadening of the THz conductivity peak.
Friday, February 19, 2016
Abstract-Microstructured gradient-index lenses for THz photoconductive antennas
Mads Brincker1, Peter Karlsen2, Esben Skovsen1 and Thomas Søndergaard1,a)
a) Corresponding author: ts@nano.aau.dk
AIP Advances 6, 025015 (2016); http://dx.doi.org/10.1063/1.4942426
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