Showing posts with label Oxford University. Show all posts
Showing posts with label Oxford University. Show all posts

Friday, May 8, 2020

Scanning with golden bow ties





Detectors would operate in terahertz region.

By Phil Dooley

https://cosmosmagazine.com/physics/scanning-with-golden-bow-ties-1

Australian and British physicists have unveiled their design for a high-precision detector they say could enable a new generation of safe compact scanners.
As described in a paper in the journal Science, it is based around tiny “bow ties”, each comprising two triangles of solid gold connected by two nanowires.
This design allows it to operate in the terahertz region of the electromagnetic spectrum, between microwaves and infrared. Terahertz scanning offers a safer low-energy alternative to X-rays: it is not powerful enough to ionise materials.
However, it still penetrates materials such as plastics, wood and paper, is absorbed by water, and is reflected by metals, giving the technology the capability to analyse a wide range of samples.
The bow ties also are able to detect the polarisation of the terahertz radiation, which adds another dimension to the detector’s versatility.
“The polarisation gives you much more useful information, especially about biological molecules, for example their chirality,” says Chennupati Jagadish from the Australian National University (ANU).
“Complex molecules have their own terahertz fingerprints, so this technology can be used for finding cancer biomarkers, locating explosives or measuring moisture levels in crops.”
The device is the result of a collaboration between ANU and Oxford University in England and Scotland’s Strathclyde University.
Importantly, the researchers say, it overcomes a limitation in the resolution, or detail, of conventional terahertz imaging, which is linked to its millimetre-scale wavelength – a million times larger than X-rays, with nanometre-scale wavelengths.
The design gets around this limitation with the microscopic scale of the bow ties. The pair of nanowires at their heart are indium phosphide wires one hundredth the size of a human hair: around 280 nanometres in diameter and ten micrometres long.
Although each detector is much smaller than the terahertz waves (around 300 microns), an array of bow ties can be used to create a near-field image that bypasses the diffraction limit of the terahertz radiation’s wavelength.
To detect the polarisation of the radiation, the team combined two bow ties, set at right angles to each other, with their central nanowires crossing but not in contact – one bow tie is set slightly above the other.
Although a simplistic-sounding design, the vertically offset configuration took three years of collaboration to devise and manufacture.
The nanowires were created at ANU, the triangles were added at Oxford as antennae to boost the signal level (gold being the obvious choice due to its high conductivity), then the devices were assembled at Strathclyde.
The team is now developing nano-scale electronics to connect to the detector, so the whole device can be built onto a single chip, in contrast with existing bulky terahertz scanners.

Monday, November 24, 2014

Vibrations reveal how material 'takes a breath'


http://tgtechno.com/nanotechnologyzone/index.php/news/research-news/3535-vibrations-reveal-how-material-takes-a-breath
A combination of supercomputer calculations and a bombardment of high-energy particles has revealed how a new kind of material opens its pores and 'breathes'. Metal-organic frameworks (MOFs), are formed from building blocks made up of metal ions connected by organic molecules. These molecular blocks assemble themselves to produce a variety of crystal-like structures whose porous nature and ‘shape-shifting’ abilities could make them ideal for emerging applications, such as trapping greenhouse gases or delivering drugs.
'One of the key selling points of MOFs is the exceptionally large internal surface area that some of the frameworks can possess,' Matthew Ryder, a DPhil student in the Multifunctional Materials & Composites (MMC) Laboratory at Oxford University's Department of Engineering Science, tells me. 'Some MOFs have internal surface areas as large as 10,000 square metres per gram and to put that into perspective, that's a larger surface than a football field in every gram of MOF material!'
Whilst MOFs are similar to traditional microporous materials, such as inorganic zeolites or the activated carbons used to filter drinking water or air, they typically have a surface area ten times greater and can be processed at much lower temperatures. MOFs can also be built from a wider range of metal ions and organic links so that the desirable characteristics, such as pore size and its functionality, can be 'fine-tuned'.
Unlike activated carbons, MOFs are highly crystalline and this means that their 3D crystal structure can be precisely determined using diffraction techniques, such as X-rays and neutrons. Accurate 3D representations of MOF structures are central to computational modelling studies.
'It has been suggested for some time that the practical functionalities of each specific MOF material is intrinsically controlled by its elastic responses and collective vibrations of the porous framework (called 'lattice dynamics') down at the molecular scale,' Matthew explains.
In a study recently published in Physical Review Letters the team, led by Oxford's Professor Jin-Chong Tan, reports a new method for investigating how MOFs vibrate. They tested their ideas on a subclass of MOF materials: Zeolitic Imidazolate Frameworks (ZIFs).
Their method used Density Functional Theory (DFT) to unravel the complete vibrational nature of the frameworks at the molecular level. These calculations were so demanding that they could only be accomplished on state-of-the-art supercomputers (at ARC in Oxford, SCRAF at Rutherford Appleton Laboratory in Harwell, and the SuperMUC Petascale System near Munich). The theory was then confirmed using high-resolution spectroscopic experiments at Diamond Light Source and the ISIS Pulsed Neutron & Muon Source at Harwell, Oxford.
The team found that the experiments closely matched the theoretical DFT predictions across the entire vibrational spectra and discovered that the most exciting MOF framework vibrational behaviour was located in the low-energy or 'Terahertz (THz) region'.
'We demonstrated for the first time that the Terahertz modes not only show the standard lattice vibrations, but also reveal all of the physical characteristics unique to the specific MOFs we studied (ZIF-4, ZIF-7 and ZIF-8),' Matthew tells me.
'Our results revealed intriguing Terahertz vibrational modes [watch animations here], which include co-operative 'gate-opening' and 'breathing' of the nano-sized pores of MOFs, crucial for the understanding of gas separation, storage, and sensing.
'Significantly, this study enabled us to gain new insights into mechanical properties of MOFs, elucidating possible phase change mechanisms (called 'soft modes') through which the porous framework may destabilise, distort or even collapse when subject to mechanical forces, thereby completely destroying their functionality. Furthermore, soft modes may give rise to anomalous and counter-intuitive mechanical behaviour, such as negative thermal expansion and auxeticity.'
By studying the Terahertz vibrations in MOFs the researchers believe they could pinpoint and overcome deformation mechanisms that could otherwise make them difficult to use commercially.
Understanding how MOFs vibrate, change shape, and 'breathe', could also make it possible to enhance how they trap specific gas molecules – such as greenhouse gases – and help to tailor them for the targeted delivery of anti-cancer drugs.
'Interestingly, the latest research into MOFs has concentrated on other less conventional applications of porous materials: everything from microelectronics and information storage, to water splitting for sustainable hydrogen production and solar energy harvesting (photovoltaics) for clean electricity generation,' Professor Tan comments.
'Engineers, materials scientists and chemists have a big role to play to ensure the future success of MOFs. Discovering more about the mechanical properties and long-term durability of these materials will be key to realising their full potential and making the leap from the laboratory into large-scale commercial applications.'

Paper: Identifying the Role of Terahertz Vibrations in Metal-Organic Frameworks: From Gate-Opening Phenomenon to Shear-Driven Structural Destabilization - Matthew R. Ryder, Bartolomeo Civalleri, Thomas D. Bennett, Sebastian Henke, Svemir Rudić, Gianfelice Cinque, Felix Fernandez-Alonso and Jin-Chong Tan - Phys. Rev. Lett. 113, 215502, DOI: http://dx.doi.org/10.1103/PhysRevLett.113.215502

Source: By Pete Wilton, University of Oxford

Thursday, September 12, 2013

Focus on Oxford Terahertz Photonics Group

My Note: I just came across this interesting webpage.
https://www-thz.physics.ox.ac.uk/

The Oxford Terahertz Photonics Group is a research group within the sub-department of Condensed Matter Physics, which is part of the sub-faculty ofPhysics at the University of Oxford. We are also a member of Oxford'sSeMicoNDuctors linkage group. We study low-energy processes in semiconductors and nanostructures on a femtosecond time-scale. Our research also involves developing novel spectroscopic techniques, for example we have recently developed a new method of terahertz time domain spectroscopy which allows the full polarisation state of terahertz pulses to be recovered.

For enquires about the group please contact:
Dr Michael B. Johnston (group leader), M.Johnston@physics.ox.ac.uk
Clarendon Laboratory, Parks Road, Oxford, OX1 3PU, United Kingdom.

Latest Publications


    table of content figure
    Dependence of Dye Regeneration and Charge Collection on the Pore-Filling Fraction in Solid-State Dye-Sensitized Solar Cells
    Weisspfennig et al. Adv. Funct. Mater., 0:ASAP (Sep 2013)
    pdf ][DOI:10.1002/adfm.201301328]

    table of content figure
    Direct Observation of Charge-Carrier Heating at WZ–ZB InP Nanowire Heterojunctions
    Yong et al. Nano Lett., 13:1 (Aug 2013)
    pdf ][ DOI:10.1021/nl402050q]
    We show that type II heterointerfaces in semiconductor nanowires can sustain a hot charge-carrier distribution over an extended time period. In photovoltaic applications, such heterointerfaces may hence both reduce recombination rates and limit energy losses by allowing hot-carrier harvesting

    table of content figure
    Electronic properties of GaAs, InAs and InP nanowires studied by terahertz spectroscopy
    Joyce et al. Nanotechnology,24:214006 (May 2013)
    pdf ][ DOI:10.1088/0957-4484/24/21/214006 ]
    Using terahertz conductivity spectroscopy, we have assessed the ultrafast electronic properties of GaAs, InAs and InP nanowires. InAs nanowires exhibited extremely high electron mobility, highlighting their immediate suitability for high mobility devices. InP nanowires exhibited the longest carrier lifetimes, highlighting their potential for photovoltaics.

    table of content figure
    Strong Carrier Lifetime Enhancement in {GaAs} Nanowires Coated with Semiconducting Polymer
    Yong et al. Nano Lett.,12:6293–6301 (Dec 2012)
    pdf ][ DOI:10.1021/nl3034027]
    We observe strong carrier lifetime enhancement for nanowires blended with semiconducting polymers. The enhancement in such inorganic-organic hybrids is found to depend crucially on the ionization potential of the polymers with respect to the Fermi energy level at the surface of the (GaAs) nanowires.

    table of content figure
    Extreme sensitivity of graphene photoconductivity to environmental gases
    Docherty et al. Nat. Commun.,3:1228 (Nov 2012)
    pdf ][DOI:10.1038/ncomms2235 ]
    We show that the photoconductivity of graphene at terahertz frequencies is dramatically altered by the adsorption of atmospheric gases, such as nitrogen and oxygen. Furthermore, we observe the signature of terahertz stimulated emission from gas-adsorbed graphene.

    table of content figure
    Ultra-low Surface Recombination Velocity in InP Nanowires Probed by Terahertz Spectroscopy
    Joyce et al. Nano Lett.,12:5325-–5330 (Oct 2012)
    pdf ][ DOI:10.1021/nl3026828]
    Using terahertz spectroscopy we measured long charge carrier lifetimes and a remarkably low surface recombination velocity in InP nanowires. We found that the carrier mobility is strongly limited by the presence of crystallographic defects, such as zinc-blende/wurtzite polytypism and stacking faults in these InP nanowires.