Showing posts with label Dane J. Phillips. Show all posts
Showing posts with label Dane J. Phillips. Show all posts

Tuesday, June 19, 2018

Abstract-A high-efficiency regime for gas-phase terahertz lasers


Fan Wang, Dane J. Phillips, Jeongwon Lee,  Henry O. Everitt

https://www.researchgate.net/publication/325702634_A_high-efficiency_regime_for_gas-phase_terahertz_lasers

We present both an innovative theoretical model and an experimental validation of a molecular gas optically pumped far-infrared (OPFIR) laser at 0.25 THz that exhibits 10× greater efficiency (39% of the Manley–Rowe limit) and 1,000× smaller volume than comparable commercial lasers. Unlike previous OPFIR-laser models involving only a few energy levels that failed even qualitatively to match experiments at high pressures, our ab initio theory matches experiments quantitatively, within experimental uncertainties with no free parameters, by accurately capturing the interplay of millions of degrees of freedom in the laser. We show that previous OPFIR lasers were inefficient simply by being too large and that high powers favor high pressures and small cavities. We believe that these results will revive interest in OPFIR laser as a powerful and compact source of terahertz radiation.

Thursday, April 5, 2012

Infrared-terahertz double-resonance spectroscopy of CH3F and CH3Cl at atmospheric pressure



Dane J. Phillips, Elizabeth A. Tanner, Frank C. De Lucia, and Henry O. Everitt
Accepted Friday Mar 30, 2012
A new method for highly selective remote sensing of atmospheric trace polar molecular gases is described. Based on infrared/terahertz double resonance spectroscopic techniques, the moleculespecific coincidence between the lines of a CO2 laser and rotational-vibrational molecular absorption transitions provide two dimensions of recognition specificity: infrared coincidence frequency and the corresponding terahertz frequency whose absorption strength is modulated by the laser. Atmospheric pressure broadening expands the molecular recognition "specificity matrix" by simultaneously relaxing the infrared coincidence requirement and strengthening the corresponding terahertz signature. Representative double resonance spectra are calculated for prototypical molecules CH sub 3 F and CH sub 3 Cl and their principal isotopomers, from which a heuristic model is developed to estimate the specificity matrix and double resonance signature strength for any polar molecule.