Abstract-Terahertz double-exponential model for adsorption of volatile organic compounds in active carbon

Jing Zhu1,2, Honglei Zhan1,2,3, Xinyang Miao1,2, Kun Zhao1,2,3 and Qiong Zhou

http://iopscience.iop.org/article/10.1088/1361-6463/aa6e2f/meta

In terms of the evaluation of the diffusion-controlled adsorption and diffused rate, a mathematical model was built on the basis of the double-exponential kinetics model and terahertz amplitude in this letter. The double-exponential-THz model described the two-step mechanism controlled by diffusion. A rapid step involves external and internal diffusion, followed by a slow step controlled by intraparticle diffusion. The concentration gradient of the molecules promoted the organic molecules rapidly diffusing to the external surface of adsorbent. The solute molecules then transferred across the liquid film. Intraparticle diffusion began and was determined by the molecular sizes, as well as affinities between organics and activated carbon.