Abstract-Dynamics of the stratification process in drying colloidal dispersions studied by terahertz time-domain spectroscopy

Jacobus L.M. van Mechelen

Langmuir, Just Accepted Manuscript

DOI: 10.1021/la503322v

Publication Date (Web): October 9, 2014

Copyright © 2014 American Chemical Society

http://pubs.acs.org/doi/abs/10.1021/la503322v

We present an optical study that reveals the bulk dynamics of the stratification process in drying colloidal dispersions. Terahertz time-domain spectroscopy has been used to measurein situ solventborne and waterborne paint layers as a function of drying time. The dynamic behavior of the dry top layer and wet bottom layer thickness, as well as the bulk thickness, reflect the principal processes of the established drying mechanism. In addition, the results demonstrate stratification only when the drying process is in the evaporation controlled regime, whereas the coating is shown to remain a single layer for diffusion controlled drying.